Autumn Leaf Cross Section
There are three major components for pigment change in leaves.
Plastids
(1) are minute leaf structures that carry green chlorophyll and color
the summer forest. Carotenoids (2), stored in plastids, and
anthocyanins (3) in sap are the leaf paints (pigments) that color the
forest of autumn.

Green plastids (figure 1): A green leaf is green because of the
presence of a group of pigments known as chlorophylls. Minute
structures called plastids contain the chlorophyll within the leaf.
When these green pigments are abundant in the leaf's cells, as they are
during the growing season, the chlorophylls' green color dominates and
masks out the colors of any other pigments that may be present in the
leaf. Thus the leaves of summer are characteristically green.
Carotenoid pigments (figure 2): These pigments are also found in
plastids. The carotenoids occur, along with the chlorophyll pigments,
in tiny structures - called plastids - within the cells of leaves.
Sometimes they are in such abundance in the leaf that they give a plant
a yellow-green color, even during the summer. But usually we become
aware of their presence for the first time in autumn, when the leaves
begin to lose their chlorophyll.
Carotenoid yellow and orange color is in many living things, giving
characteristic color to carrots, corn, canaries, and daffodils, as well
as egg yolks, rutabagas, buttercups, and bananas. Their brilliant
yellows and oranges tint the leaves of such hardwood species as
hickories, ash, maple, yellow-poplar, aspen, birch, black cherry,
sycamore, cottonwood, sassafras, and alder.
Anthocyanin pigments (figure 3): These pigments occur in the sap of
cells. The anthocyanins temporarily color the edges of some of the very
young leaves as they unfold from the buds in early spring. They also
give the familiar red and purple color to such common fruits as
cranberries, red apples, blueberries, cherries, strawberries, and plums.
In an autumn forest they show up vividly in the maples, oaks, sourwood,
sweetgum, dogwood, tupelo, black gum, and persimmon. These same
pigments often combine with the carotenoids' colors to give us the
deeper orange, fiery reds, and bronzes typical of many hardwood species.
(Information for this page found at About.com)